To identify possible alternatives to acetone for ink removal
Date Run:
05/31/2002
Experiment Procedure:
Nine products were selected from the lab's databases based on supplied information. Six cleaners were used at 10% solutions diluted in 600 ml beakers using DI water. The other three products were used at full strength. All nine products were heated to 130 F on a hot plate. Twenty-seven preweighed glass coupons were coated with a layer of Essilor Yellow Ink Y368 Akyl resin printing ink (107-87-9, 123-86-4, 108-65-6, 1330-20-7) using a hand held swab. Once the ink was dry, a second weighing was recorded. Three coupons were cleaned in each solution for 5 minutes using only stir-bar agitation. After cleaning, the coupons were rinsed in a tap water bath for 15 seconds at 120 F and dried for 15 seconds using a Master Appliance Heat Gun at 500 F. Final weights were recorded and efficiencies calculated.
Trial Results:
None of the aqueous products selected were effective in cleaning the ink from the glass (ND 17, Crystal Simple Green, Shopmaster LpH, Daraclean 235). In two cases the ink weight was increased due to the cleaners penetrating into the ink causing swelling (ND 17, Crystal Simple Green). The two terpenes removed over 90% of the ink (Bio T Max, OptiClear). The two esters used removed similar amounts as the terpenes (7360, Methyl Ester 1816). The alcohol based product removed around 70% of the ink (Misprint Stencil Remover). The table below lists the amount of contaminant applied and removed. For the terpene and esters, there were some issues with obtaining proper rinsing. This issues may be improved by using a spray in place of the tap water bath rinse.
Table 1. Contaminant Cleaning
Table 1. Contaminant Cleaning
Cleaner
Applied
Remaining
% Removed
Bio T Max
0.0354
0.0019
94.63
0.0124
0.0025
79.84
0.0641
0.0034
94.70
OptiClear
0.0352
0.0012
96.59
0.0371
0.0004
98.92
0.0366
-0.0005
101.37
7360
0.0120
0.0013
89.17
0.0180
0.0011
93.89
0.0116
0.0013
88.79
ND 17
0.0109
0.0137
-25.69
0.0152
0.0230
-51.32
0.0236
0.0297
-25.85
Crystal SG
0.0268
0.0306
-14.18
0.0170
0.0273
-60.59
0.0139
0.0341
-145.32
1618
0.0259
0.0019
92.66
0.0224
0.0009
95.98
0.0182
0.0000
100.00
Shopmaster
0.0222
0.0221
0.45
0.0271
0.0267
1.48
0.0129
0.0126
2.33
Misprint
0.0415
0.0197
52.53
0.0372
0.0033
91.13
0.0144
0.0054
62.50
Daraclean
0.0253
0.0233
7.91
0.0334
0.0293
12.28
0.0305
0.0217
28.85
Success Rating:
Results successful using TACT (time, agitation, concentration, and temperature, as well as rinsing and drying) and/or other cleaning chemistries examined.
Conclusion:
The four successful products will used in the second trial. The next trial will attempt to improve efficiencies through increased concentrations for the esters and tap water spray rinse for all.
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